This study aimed to investigate the relationship between perfectionism, narcissism, and flexibility with emotional divorce among working women. The study population consisted of all women working in Education in Tehran in 2016. We selected 356 subjects as samples by cluster sampling from among the population. They filled out questionnaire of emotional divorce, narcissism, perfectionism, and flexibility. Method of the study was descriptive-correlational. We used correlation and stepwise regression for data analysis. The results of Pearson correlation showed a negative relationship between positive perfectionism and emotional divorce, and a positive relationship between negative perfectionism and emotional divorce. There is a positive relationship between narcissism and emotional divorce, and a negative relationship between flexibility and emotional divorce. The results of stepwise regression showed that negative perfectionism predicts 33.1%, narcissism 7.1%, flexibility 3.2%, and perfectionism 1.3% of the changes of emotional divorce. Overall, these variables are able to predict about 44.7% of the changes in emotional divorce.